Organic Nonlinear Optical Materials

The nonlinear optical material is a general term for the materials efficiently make appearance of nonlinear phenomenons optically as the responses to optical wavelength conversion, optical amplification as well as the refractive index changes due to its intensity. Nonlinear optical materials are largely divided into inorganic and organic materials. In 1930, the nonlinear optical effect related to optical wavelength conversion was predicted, which was said to be the first finding knowledge about the nonlinear optical phenomenon. In 1960, laser oscillation using inorganic material was reported. Since then researches of inorganic nonlinear optical materials were actively taken place, but now-a-days, probably there is no more that undiscovered.
On the other hand, the 1982 ACS symposium report added momentum to the organic nonlinear optical material studies. Since then the studies have started to become active. It revealed organic compounds with the delocalized conjugated electrons which have excellent nonlinear optical property and high-speed responsiveness due to high mobility of electrons.
The 21st Century is said to be an age of photonics. As one of the basic technology of photonics, improvements of the wavefront control technology using organic nonlinear optical effects are considered very important. Now R&D on the organic materials with excellent nonlinear optical properties, and vigorous applied studies have been carried out.

A0621 A0621 A1251 A1251 A0794 A0794
A0838 A0838 C0943 C0943 C0214 C0214
C1209 C1209 C1349 C1349 D2020 D2020
D2263 D2263 D2505 D2505 D0289 D0289
D2135 D2135 H0747 H0747 M0997 M0997
M0999 M0999 M0909 M0909 M0985 M0985
M1677 M1677 N0529 N0529 N0527 N0527
M0953 M0953 N0117 N0117 N0118 N0118
N0119 N0119 N0400 N0400 N0547 N0547
N0546 N0546 N0540 N0540 N0281 N0281
A0621 2-Aminofluorene
A1251 4-Amino-4'-nitrobiphenyl
A0794 2-Amino-5-nitropyridine
A0838 2-Amino-3-nitropyridine
C0943 2-Chloro-3,5-dinitropyridine
C0214 2-Chloro-4-nitroaniline
C1209 2-Chloro-4-nitro-N-methylaniline
C1349 N-Cyanomethyl-N-methyl-4-nitroaniline
D2020 2'-(N,N-Dimethylamino)-5'-nitroacetanilide
D2263 4-Dimethylamino-4'-nitrobiphenyl
D2505 4-Dimethylamino-4'-nitrostilbene
D0289 1,3-Dimethylurea
D2135 N-(2,4-Dinitrophenyl)-L-alanine Methyl Ester
H0747 4-Hydroxy-4'-nitrobiphenyl
M0997 4-Methoxy-4'-nitrobiphenyl
M0999 4-Methoxy-4'-nitrostilbene
M0909 (R)-(+)-2-(alpha-Methylbenzylamino)-5-nitropyridine
M0985 (S)-(-)-2-(alpha-Methylbenzylamino)-5-nitropyridine
M1677 3-Methyl-4-nitroaniline
N0529 2-Methyl-4-nitroaniline
N0527 3-Methyl-4-nitropyridine N-Oxide
M0953 N-Methyl-4-nitro-o-toluidine
N0117 3-Nitroaniline
N0118 2-Nitroaniline
N0119 4-Nitroaniline
N0400 5-Nitroindole
N0547 (S)-(-)-N-(5-Nitro-2-pyridyl)alaninol
N0546 (S)-N-(5-Nitro-2-pyridyl)phenylalaninol
N0540 (S)-(-)-N-(5-Nitro-2-pyridyl)prolinol
N0281 5-Nitrouracil

Purification just before use is recommended.

Literature

1) S. Miyata, et al., Preprints of IUPAC 32nd International Symposium on Macromolecules, Kyoto, 1988, p.582.
2) D. S. Chemla, J. Zyss, “Nonlinear Optical Properties of Organic Molecules and Crystals”, Academic Press, New York, 1987.
3) L. M. Hayden, S. T. Kowel, M. P. Srinivasan, Optics Comm., 1987, 61, 351 [DOI].
4) C. Flytzanis, J. L. Oudar, “Nonlinear Optics: Materials and Devices”, Springer, Berlin, 1986.
5) P. N. Prasad, D. R. Ulrich, “Nonlinear Optical and Electroactive Polymers”, Plenum, New York, 1988.
6) D. R. Ulrich, J. Orenstein, A. J. Heeger, “Nonlinear Optical Properties of Polymers”, Material Research Society, Pittsbourgh, 1988.


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