Structure
| TCI Product No. : | B3161 | |||||||||
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| Stock Status : |
Status at 03:00 a.m. on Feb 09, 2012 (IST) * Items available from stock in Japan will be delivered in 7 business days |
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| Purity / Analysis Method : | >98.0%(T) | |||||||||
| Storage : | Freezer | |||||||||
| M.F. / M.W. : | C24H54P2Pd=511.06 | |||||||||
| CAS Number : | 53199-31-8 | |||||||||
| Related CAS Number : | ||||||||||
| MDL Number : | MFCD03094580 |
Newman-Kwart Rearrangement of Thiocarbamates Typical Procedure: An ampoule is charged with the thiocarbamate (0.442 mmol) and anhydrous degassed toluene (4 mL) is added via gastight syringe under nitrogen with stirring. A J. Youngs valve is fitted and the ampoule is placed into an oil bath pre-equilibrated at 100℃. After ca. 5 minutes the valve is removed and Pd(t-Bu3P)2 (2 mol%, 0.00884 mmol) is added as a solid, the valve is then replaced and the reaction mixture heated for 2.5 hours. A sample of the reaction mixture is removed via gastight syringe and found to contain the desired product (＞99%). |
| TCI MAIL : | |
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| TCI Product Literature : | |
| Related Categories : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Pd (Palladium) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Palladium Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Palladium Catalyst (for Suzuki-Miyaura Cross-coupling) |